Will this package sync up to any of the rock lights so they all flash the same colors? If so, will extra parts be needed to do so?

Hello, this package can sync up to any of the rock lights so they all flash the same colors. There will be an extra line in the controller.

Can I have the light bar and two spot pods up front and the other two flood pods on the back of the vehicle? If so, Will I be able to operate them separately? I want to be able to turn the light bar and two pods on separately from the other two flood pods but also able to use them all at the same time as well. Is this possible?

Yes, you can have the light bar and two spot pods up front and the other two flood pods on the back of the vehicle. And with SS WIRELESS REMOTE CONTROLLER,  you can operate them separately and operate them at the same time as well.